
Effects
of Brine: Specialist Report (972Kb)

Brine Scoping Report on
GrahamTek Seawater RO System (8.7Mb)
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1. WHAT IS THE CHARACTERISTICS OF WATER?
2. WHAT IS CONDUCTIVITY/RESISTIVITY?
3. WHAT IS MICROBIAL CONTAMINATION?
4. WHAT IS PH?
5. WHAT IS REVERSE OSMOSIS
6. HOW IS OUR MUNICIPAL WATER TREATED?
7. HOW MUCH POWER IS NEEDED TO PRODUCE A KILOLITRE OF DESALINATED WATER AND WHAT
IS THE COST OF CAPITAL FOR A KILOLITRE?
8. IS IT POSSIBLE TO RUN A DESALINATION PLANT ON SOLAR ENERGY?
9. WHAT CAN BE REMOVED FROM WATER BY MEMBRANES?
Other:

Reverse Osmosis
Do you think South Africa should be looking at new technology such as
desalination or be tackling the roots of our water shortage problems such as
unsustainable agriculture and urban use of water. Is desalination just another
quick fix? After all is appears that every time humans alter a natural system
other problems arise?
What happens to the excess salt produced by desalination? Is it useful or just a
waste product? If it is a waste product is it dumped out to sea where it can
potentially harm marine life?
In its pure state water is one of the most aggressive solvents known to
man.
Called the universal solvent, water to a certain degree, will dissolve virtually
everything to which it is exposed.
Pure water has a very high energy state, and like everything else in nature,
seems to reach energy equilibrium with its surroundings.
It will dissolve the quantity of material available until the solution reaches
saturation, the point at which no higher level of solids can be dissolved.
Contaminants found in water include: Natural gases, minerals, organic materials
(some natural, some man- made) plus any materials used to transport or store
water.
The molecular weight of water can be calculated as such:
(MW): The weight of 602,200,000,000,000,000, 000, 000 (6.022X10²³) molecules of
a substance. Calculated by adding up the individual atomic weights (AW) of the
atoms comprising a molecule.
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Ions conduct electricity. Because water contains few ions, it has a high
resistance to electrical current. The measurement of water’s conductivity or
Resistivity provides an assessment of total ionic concentration.
Conductivity is described in micro Siemens/cm (μS), and measured with a
Conductivity meter. Resistivity is described megohm/cm, and is the inverse of
conductivity, and measured by Resistivity meter.
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There
are two types of this contamination namely, viable, and non-viable.
Viable can reproduce an proliferate.
Non Viable cannot reproduce or multiply
Types of Microbiological Contamination are:
- Bacterial Contamination
- Pyrogenic Contamination
- Total Organic Carbon (TOC)
- Biochemical Oxygen Demand (BOD)
- Chemical Oxygen Demand (COD)
BACK
The relative acidic or basic level of a solution is measured by pH.
The Ph is a measure of Hydrogen Ion concentration in water, specifically the
negative logarithm (log) of the hydrogen ion concentration.
The measurement of pH lies in the scale of 0 – 14, with a pH of 7.0 being
neutral. This means that the water is neither acidic, nor basic. It also bears
equal numbers of hydroxyl (OH-) and hydrogen (H+) ions.
A pH of less than 7.0 is acidic, and more than 7.0 is basic.
BACK
WHAT IS REVERSE
OSMOSIS?
What is osmosis? It is the phenomenon of water flow through a semi permeable
membrane that blocks the transport of salts or other solutes through it. Osmosis
is a fundamental effect in all biological systems. It is applied to water
purification and desalination, waste material treatment, and many other chemical
and biochemical laboratory and industrial processes.
When two water (or other solvent) volumes are separated by a semi permeable
membrane, water will flow from the side of low solute concentration, to the side
of high solute concentration. The flow may be stopped, or even reversed by
applying external pressure on the side of higher concentration. In such a case
the phenomenon is called reverse osmosis.
If there are solute molecules only in one side of the system, then the pressure
that stops the flow is called the osmotic pressure.
Reverse Osmosis (RO) was invented in 1959 by Prof Reid of the University of
Florida, and was put into practical use by Sidney Loeb and Srinivasa Sourirajan.
It is a process which removes both dissolved organics and salts.
Feedwater is pressurized and flows across a membrane, with a portion of the feed
permeating the membrane. The balance of the feed sweeps parallel to the surface
of the membrane to exit the system without being filtered. The filtered stream
is the permeate, because it has permeated the membrane. The second stream is the
concentrate because it carries off the concentrated contaminants, rejected by
the membrane.
Because the feed and concentrate flow parallel to the membrane and not
perpendicular to it, the process is called “cross flow filtration”.
Depending on the size of the pores engineered into the membrane, cross flow
filters are effective in the classes of separation known as Reverse Osmosis,
nano filtration, ultra filtration and micro filtration.
See “Filtration spectrum”
Cross flow membrane filtration allows continuous removal of contaminants which
in normal flow filtration would blind (plug) the membrane pores rapidly, in
conventional systems. (GrahamTek changed this technique successfully)
* Crossflow vs Dead end filtration discussed later in this document
RO removes most organic compounds and up to 99% of all ions.
A selection of RO membranes can be used to treat different feedwater scenarios.
It can meet almost all water standards with a single pass system and all water
standards with a double pass system. The process achieves rejections of 99.9% of
viruses, bacteria and pyrogens. Pressure in the range of 3.4 – 70 Bar is the
driving force of the RO purification process.
It is much cheaper than most conventional treatment systems today, and with
GrahamTek Proprietary technology, removes the need for pre-treatment chemicals.
There are a few types or methods of Reverse Osmosis:
- Nano Filtration (NF)
Removes organic compounds, and rejects some salts with low pressures being
applied. It is the process normally used for mildly salty tasting water, or as a
water softening technique.
- Ultra filtration (UF)
BACK
Similar to RO and NF, but does not reject ions. It operates at low pressures
(0.7-6.9 Bar). It removes larger organics, colloids, bacteria and pyrogens while
allowing most ions and small organics such as sucrose to permeate the porous
structure.
- Micro filtration (MF)
Micro filter membranes are absolute cut-off filters rated in the 0.1-3.0 micron
range.
ADSORPTION: Adsorption is the binding of a molecule to a surface (solid
or liquid) by non-specific physical forces. For example, the removal of free
chlorine and chloramines by activated carbon is through the mechanism of
adsorption.
AERATION: A process in which air is intimately mixed with water to remove
undesirable gases, such as carbon dioxide and hydrogen sulfide. Carbon dioxide
can be more economically removed from water by aeration than by chemical
precipitation or by the use of ion exchange resins.
ALKALINITY: Capacity of water to accept acid, ordinarily because of its
bicarbonate content. In some cases a part of the alkalinity in water may be do
to carbonate, hydroxide, phosphate, or silicate. It is expressed in terms of
mg/l of calcium carbonate. Total alkalinity is determined by titration with acid
to a pH of 4.3. Methyl orange indicator is frequently used as the end point, but
potentiometric titration is preferable.
If the pH of the water is greater than 8.3, it is probable that carbonate is
present. Carbonate alkalinity is determined by titration with acid to pH 8.3
(phenolphthalein indicator).
ANION: A particle of matter dissolved in water that has a negative
charge. In each system of matter the number of anions is equal to the number of
cations (positively charged ions).
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BACTERIA: Bacteria are single cell microorganisms capable of replicating
on their own. They can be divided into two broad categories: aerobic (requiring
oxygen) and anaerobic (not requiring oxygen). Bacteria can live in a very broad
range of habitats. Some, for example pseudomonads, can thrive in environments
containing very low level of nutrients. These bacteria are frequently slime
producers and are a major problem in water treatment systems. Other bacteria,
which adhere to surfaces, secret gelatinous material which serves to protect the
bacteria from chemical disinfectants. This combination of bacteria and their
protective coating is sometimes referred to as biofilm. The concentration of
bacteria in water is commonly given in terms of colony forming units (cfu) per
ml. A colony forming unit is a viable bacterium able to replicate to form a
whole colony when incubated in a given environment.
BICARBONATE: Bicarbonate is formed in water by the reaction of carbon
dioxide with mineral matter, such as limestone or dolomite. The carbon dioxide
is absorbed from air or from decaying organic matter, and the bicarbonate that
is formed imparts alkalinity to water. See Alkalinity. Calcium and magnesium
bicarbonate do not exist in solid form. When water is removed from solutions of
these salts, they lose carbon dioxide and form calcium and magnesium carbonate.
BLOWDOWN: Discharge of water containing concentrated dissolved solids
that is replaced by water containing less concentrated dissolved solids. It is
conventionally used in connection with the operation of boilers and cooling
towers. It is also sometimes used as a term for the concentrate from the reverse
osmosis process.
BOD: Abbreviation for Biochemical Oxygen Demand. It is an emperical test
used on wastewater in which organisms capable of oxidizing organic matter are
introduced. The test is not precise. See COD.
BOUNDARY LAYER: A very thin liquid layer immediately adjacent to the
rejecting surface of reverse osmosis membranes in which the concentration of
dissolved solids is higher than it is in the main body of the water being
processed. The phenomenon is known as concentration polarization.
BRACKISH WATER: Water containing between 1,000 mg/l and 15,000 mg/l of
dissolved solids is generally considered to be brackish.
BACK
BRINE: Another term for
concentrate.
BRINE SEAL: A U-cup of synthetic rubber attached to the upstream end of a
membrane element. It is activated by water pressure to form a joint with the
inner surface of the pressure vessel in which the module is placed to prevent
water from bypassing around the module.
BUFFER: A substance or combination of substances that resist a change in
pH when an acid or an alkali is added to water in which they are dissolved.
BUFFER SOLUTION: A solution of salts that is used to calibrate pH meters.
Different combinations of salts are used to prepare buffer solutions with
different pH values.
CALCIUM BICARBONATE: A salt that is present in most natural waters. Water
containing calcium bicarbonate loses carbon dioxide when it is evaporated or
concentrated by reverse osmosis and calcium carbonate is precipitated.
CALCIUM CARBONATE: Occurs in nature as limestone. It dissolves in water
containing carbon dioxide by forming calcium bicarbonate.
CALCIUM SULFATE: Commonly called gypsum. It is sparingly soluble and
precipitates when water is removed from saturated solutions of the salt.
CARBONATE HARDNESS: See
Hardness.
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CATION: A particle of matter dissolved in water that has a positive
charge. In each system of matter, the number of cations is equal to the number
of anions (negatively charged ions).
COAGULATION: A process in which small particles of suspended matter are
combined by chemical means into larger particles to effect more rapid settling
or better filtration. The most widely used coagulant is alum. Other coagulants
that are sometimes used are sodium aluminate, ferric chloride, lime and
magnesium oxide. Polyectrolytes are frequently used as coagulant aids.
COD: Abbreviation for Chemical Oxygen Demand. It is a test used on
wastewater in which a strong chemical oxidizing agent react with some of the
organic matter in the water. The test is more precise than the BOD test, but it
does not measure all of the organic matter in the water. See TOC.
BACK
COLORIMETRIC TITRATION: A titration in which a change in color is used to
measure the end point.
COMPACTION: A change in the physical structure of RO membranes caused by
exposure to excessive pressure and/or temperatures which result in a decreased
ability to produce permeate.
CONCENTRATE: Water that is rejected in the process of reverse osmosis
which contains dissolved solids in the water being processed in more
concentrated form.
CONCENTRATION
POLARIZATION: See "Boundary Layer".
CONDUCTIVITY: The ability of an aqueous solution to carry electric
current depends on the presence of ions in the solution. Conductivity is a
quantitative measure which describes this ability. Solutions of inorganic ions
are relatively good conductors (and exhibit high conductivity), whereas
solutions of organic molecules are rather poor conductors (and exhibit low
conductivity). Highly purified water is also a poor conductor. Conductivity is
expressed in units of Siemen/cm (previously known as mhos/cm). Conductivity
measurements are typically encountered in monitoring the performance of reverse
osmosis equipment. Conductivity is temperature dependent and should be measured
with a temperature-compensated meter. The usual reference temperature is 25ºC.
Conductivity measurements are sometimes used to estimate total dissolved solids
in water. While convenient, this practice is imprecise. (See also Resistivity.)
DEIONIZATION (DI): Use of ion exchange resins to demineralize water. See
Ion Exchange.
DISINFECTION: Disinfection is the process of killing micro-organisms,
usually by one of a variety of chemical agents, such as formaldehyde and sodium
hypochlorite. Disinfection lowers the number of micro-organisms without
necessarily killing all those present. Although total killing of all organisms
is virtually impossible, sterilization will reduce the number of organisms to a
safe predetermined level. Sterilization can generally only be achieved routinely
by heat, gamma irradiation, ethylene oxide, and, in certain cases, special
filtration. Of these methods, only filtration is suitable for mass sterilization
of water and none is suitable for sterilization of water treatment equipment
used in hemodialysis facilities. However, a proprietary chemical disinfectant
incorporating paracetic acid as the active ingredient has recently qualified as
a sterilant and this agent may be suitable for sterilization of certain water
system components.
DO: Abbreviation for
Dissolved Oxygen.
DRY RESIDUE: Amount of dissolved solids in water determined by
evaporating a sample to dryness and heating. The heating is usually done at
220°F (105°C) and at 355°F (180°C). Dry residue is almost always not equal to
total dissolved solids because bicarbonate loses carbon dioxide in the heating
process, and some of the dry salts that are formed retain water of hydration.
BACK
FLOW VELOCITY: The flow of fluid at any point in a water treatment system
may be expressed quantitatively in two ways, either in terms of the volume of
fluid passing the point in a given time (volumetric flow rate) or in terms of
the velocity with which fluid passes the point (flow velocity). The flow
velocity (V) depends on the geometry of the conduit through which the fluid
flows and is related to the volumetric flow (Q) by:
V = Q/A
Where: A is the cross-sectional area of the conduit. As an example, Table F.1
shows the volumetric flow rate as a function of flow velocity in PVC schedule 80
pipes of different diameters. (The values in Table F.1 are based on actual,
rather than nominal, pipe diameters.) Note that for such calculations, it is
essential that consistent units be employed. Thus, the term Q would be expressed
as ft³/sec and A as ft² to yield V as ft/sec.
FLUIDIZATION: A flowing liquid impinging on a bed of particles imparts
some of its momentum to each particle. The imparted momentum is in the direction
of the fluid flow. The particles are held to the floor of their container by
gravity and to each other by adhesive forces. If the fluid flow is upward
through the bed of particles, and if the transfer of momentum from the fluid to
the particles is sufficient to overcome both the gravitational and the adhesive
forces, the particles become suspended, of fluidized, in the fluid stream.
FLUX: A term that is commonly used for the flow rate of water through
reverse osmosis membranes.
FOULING: Deposition of solid substances on the surface of the reverse
osmosis membrane or in ion exchange resin particles. Fouling can be due to the
presence of suspended solids, sparingly soluble salts, or biological growth.
Fouling reverse osmosis membranes causes a decrease in both the amount of water
produced and the quality of the water. The performance of fouled membranes can
usually be restored by appropriate cleaning procedures. Fouling of Ion Exchange
resins causes a loss of efficiency and sometimes necessitates replacement of the
resins in the beds.
FRENCH DEGREE: Sometimes used as a unit of measure for any dissolved
substance, but it is most frequently used as a measure of hardness. It is usually
abbreviated as °F, and it is equivalent to 10 mg/l of calcium carbonate. See
Hardness.
GERMAN DEGREE: Sometimes used as a unit of measure for any dissolved
substance, but it is most frequently used as a measure of hardness. It is
usually abbreviated as °d, and it is equivalent to 17.9 mg/l of calcium
carbonate. "See Hardness".
BACK
GRAINS OF HARDNESS: Although the theoretical hardness of water is the sum
of the concentrations of all metallic ions, other than the alkali metals, it is
commonly expressed as the equivalent concentration of calcium carbonate in
grains. Ionic concentrations can be expressed in terms of their combining
potential (Eq/L), the number of moles present (mol/L), or their masses in any of
several conventions. In the English system masses are expressed in terms of
pounds (avoirdupois) which contains 7000 grains each. Although considered
outdated in most of the world, the U.S. water purification industry continues to
express hardness in units of grains/gal expressed as calcium carbonate.
Grains/gal expressed as calcium carbonate can be converted into metric units
(mg/L) by multiplying the former by 17.1. Grains/gal expressed as calcium
carbonate can also be converted into mEq/L of a univalent ion, such as sodium
(Na+) by multiplying by 0.342.
GREENSAND: Manganese Zeolite. A bed of greensand granules used for the
removal of iron and manganese from water. The greensand is a naturally occurring
mineral that has cation exchange properties. The bed is first treated with
manganous chloride to convert it to the manganese form and then it is activated
(and subsequently regenerated in repetitive cycles) with potassium permanganate.
In use, soluble iron and manganese in water precipitate on the granules, and
these solids are backwashed out of the bed at the end of each cycle.
HARDNESS: Hardness was originally defined as a measure of the ability of
water to precipitate soaps made from fatty carboxylic acids. These "soaps"
precipitated in the presence of calcium and/or magnesium ions. Today, hardness
is used to describe the total concentration of calcium and magnesium, expressed
as mg/L of calcium carbonate. It is generally calculated from measurement of
calcium and magnesium in ion concentrations using:
Hardness (mg CaCO3/L) =2.497 x Ca (mg/L) + 4.118 x Mg (mg/L)
HYDROGEN SULFIDE: A gas which is more toxic than hydrogen cyanide. it has
an offensive rotten egg odor, and it is present in some ground waters as a
result of microbial action on organic matter under anaerobic conditions. Its
odor can be detected at concentrations of a few tenths in an mg/l in water.
HYDROLYSIS: Chemical degradation of a substance by water that is usually
accelerated by acids or alkalis.
ION: A charged particle of matter. In each system of matter, the number
of positive ions (cations, such as sodium) is equal to the number of negative
ions (anions, such as chloride).
BACK
ION EXCHANGE: Ion exchange is based on the principle of
electro neutrality, that is, charged species are stable only when they exist as
balanced pairs of positive and negative charges. Ion exchange resins, the
materials used to carry out the process of ion exchange, are particles which
contain fixed charges on their surface. To maintain electro neutrality, each of
these charges has an ion of equal and opposite charge held to it; these ions are
called counter ions. The counter ions are mobile and can leave the fixed charge
if some other counter ion is available to replace it. The replacement ion must
be of the same charge as the initial counter ion in order to maintain
electro neutrality. The initial counter ion is established by washing the resin
with a concentrated solution of the desired counter ion. For example, softener
resins are cation exchangers containing carboxylic acids on their surfaces. If
these resins are washed with strong NaCl solutions, the predominant cation
solution is Na+ and it will become the counter ion. In use, the perfusing water
will provide competing counter ions, such as Ca2+. Because of the preference of
carboxylic acids for Ca2+ over the Na+ in dilute solutions, the water will be
depleted of the Ca2+ in exchange for the Na+ initially present.
IONIC STRENGTH: Some properties of dissolved solids, such as the
solubility of calcium sulfate and calcium carbonate, are affected by ionic
strength.
LANGELIER SATURATION INDEX: The precipitation of calcium and magnesium
carbonates in water purification systems is a serious cause of system failure.
The insolubility of these compounds is a complex function of the pH of the
water, the dissolved carbon dioxide content, the carbonate content, the presence
of other salts, and the temperature. The Langelier Saturation Index is a method
of predicting whether or not carbonate deposits will form under given
conditions. Calculation of the Langelier Saturation Index is complex and will
not normally be done by hemodialysis personnel. Reverse Osmosis vendors may use
the index in determining the maximum recovery and rejection rates that can be
obtained from a reverse osmosis system before carbonate deposits will seriously
reduce water quality and recovery.
Note: It should be noted that the utility of such determinations is limited to
those situations in which a softener is not used as part of the pre-treatment
scheme for reverse osmosis.
MATERIALS BALANCE: The amount of dissolved substances in the permeate
plus the amount in the concentrate must equal the amount of the feedwater.
Since the volume of the permeate is a fraction corresponding to the recovery of
the feedwater volume rate and the volume of the concentrate is a fraction
corresponding to one minus the recovery rate, materials balance is calculated
from the equation: Materials
Balance = RCp + Cc (1-r)
_______________
Cf
BACK
OSMOSIS: A natural phenomenon in which water diffuses through a membrane
from a less concentrated solution of salts to a more concentrated solution of
salts.
OSMOTIC PRESSURE: When a solution, such as salt water, is separated from
pure water by a membrane which is impermeable to the salt, a flow of water will
occur from the pure water to the salt solution. The driving force for this flow
is called the osmotic pressure and its magnitude depends on the number of salt
particles in the solution.
Note that the osmotic pressure depends on the number of particles and not on the
total mass of particles. For example, 1 g/L of a small solute, such as sodium
chloride, will exert a greater osmotic pressure than 1 g/L of a large solute,
such as protein. For water to flow from the salt solution to the pure water this
solution must be exposed to a hydrostatic pressure greater than its osmotic
pressure. This is the principle of reverse osmosis
POTENTIOMETRIC TITRATION: A titration in which a rapid change in pH is
used to measure the end point.
PRESSURE, APPLIED: The pressure in the feedwater supplied by the high
pressure pump.
PRESSURE DROP: Expenditure of a certain amount of energy is required for
a fluid to flow through any channel, such as a pipe, particle bed, or membrane.
The pressure at any point is a measurement of the energy content of the fluid at
that point. Since some of this energy is expended in flowing to a second point
downstream, the pressure at the downstream point is less than at the original
point. The amount of energy expended, and hence the decrease in pressure (or
pressure drop), is dependent on the flow rate and viscosity of the fluid, and
the size and shape of the channel. Pressure drops are usually expressed in terms
of lb/in2 or psi, or in the SI system, kPa (kilopascals). Pressure drop is
sometimes referred to colloquially as "delta P".
PRESSURE, NET: Net applied pressure minus average osmotic pressure.
PRESSURE, NET APPLIED: The average of the pressure in the feedwater and
the pressure in the concentrate upstream from the pressure control valve.
BACK
PRESSURE, EFFECT ON OUTPUT: RO output varies directly with Net Pressure
RECOVERY RATE: The percentage of water being processed by reverse osmosis
that is produced as permeate.
REJECTION RATE: When hydraulic pressure is applied to water in contact
with reverse osmosis membranes, water diffuses through the membranes and the
dissolved solids that were in the water are repelled. The degree to which they
are repelled is the rejection rate. The rejection rate decreases as the
feedwater flows through a reverse osmosis unit because the dissolved solids in
it are becoming progressively more concentrated. The net result is that the
overall rejection rate depends upon the average concentration of dissolved
solids in the entire unit.
RESISTIVITY: Resistivity is a measure of the ability of a substance, such
as water, to carry an electric current. It is expressed in units of ohm-cm and
is the reciprocal of conductivity. Resistivity measurements are commonly used to
asses the quality of water produced by deionizers. Like conductivity,
Resistivity is temperature dependent and should be measured with a
temperature-compensated meter. The usual reference temperature is 25ºC.
SILT DENSITY INDEX: The silt density index (SDI) is a measure of the
ability of water to foul a membrane or plug a filter. SDI is measured suing an
apparatus which typically consists of an inlet pressure regulator and pressure
gauge followed by a filter holder containing a 0.45 µm micro porous membrane
filter. Commercial test kits, complete with instructions on how to calculate the
index, are available.
BACK
TOTAL ORGANIC CARBON: Organic compounds dissolved in water are
characterized by their carbon content. Total organic carbon is the mass of
carbon present in a water sample, excluding the carbon present as CO2 and/or
carbonates. The values are determined by catalytically oxidizing (burning) all
dissolved carbon (after CO2/CO3= removal by acidification) to CO2. The resulting
CO2 may be measured directly by infra-red absorption, or it may be reduced in a
furnace with hydrogen to form methane, which is measured by flame ionization
detectors.
TURBIDITY: Turbidity is a measure of the presence of colloidal matter in
the water that remains suspended. Suspended matter in a water sample, such as
clay, silt, or finely divided organic and/or inorganic matter will scatter the
light from an incident light beam. The extent of scattering is expressed in
Jackson or Nephelometric turbidity units (JTU and NTU, respectively).
BACK
HOW IS OUR WATER TREATED IN
SOUTH AFRICA
The water treatment process used in South Africa is based on the use of chlorine
as the disinfectant. The water intake to the treatment plant is from dams and
rivers and it first passes through wire screens that remove any solid objects.
Typically the water would then be pre-treated with chlorine to inactivate
disease-causing pathogens. This is then followed by a mixing, coagulation and
flocculation process, where a chemical coagulant is used to enable the
microscopic dirt particles to coagulate into larger flocs, which then sink to
the bottom of the sedimentation tank. The clear water is decanted from the top
of these sedimentation plants and is passed through large filters made of sand
and gravel that remove all the suspended matter. Finally, chlorine is added to
kill any remaining germs and the treated water is tested to make sure it is safe
for drinking before being pumped to reservoir tanks from which it is transferred
as drinking water through a network of pipes to the consumer. Chlorine remains
active in the water for some six to eight hours and Rand Water adds another
chemical, namely monochloramine (a mixture of chlorine and ammonia) to the water
at its booster pumping stations. Although less active than chlorine, the
monochloramine protects the water against bacteria for up to eight days.
HOW MUCH POWER IS NEEDED TO PRODUCE A KILOLITRE OF
DESALINATED WATER AND WHAT IS THE COST OF CAPITAL FOR A KILOLITRE?
Typically these days the energy required is about 3 kWh per kilolitre. There is
a demonstration project underway in the U.S. where they anticipate dropping
energy to 1.7 kWh. The typical cost range for large plant is 0.5 to 0.65 $US per
kilolitre (i.e. less than 0.8 $A). The costs have dropped by a factor of three
in the last 10 years.
- Prof Tony Fane, Director, UNESCO Centre for Membrane Science and Technology
The current power consumption for seawater desalination is less than 3 kWh/m3,
which is a 90% reduction in energy use over the past 40 years. This is because
of improvements in membrane technology and energy recovery systems. The cost of
desalting seawater has also reduced in recent years, with the newest reverse
osmosis plants in Israel and Singapore producing water for about $US 0.50 per
metre cubed.
This price can vary significantly depending on whether it has the distribution
costs included or not. For Perth, about half the capital cost is associated with
distribution of the treated water rather than the desalination process. However,
the energy use is still about four times greater than the thermodynamic minimum
energy required for separating salt from seawater (0.8 kWhr/m3).
For desalination of wastewaters and groundwaters, the energy required is
significantly less and the cost is usually less than 50% of that for seawater
desalination and maybe as low as $A 0.20 per metre cubed for blended potable
water from groundwater. This leads us to then consider using reverse osmosis for
wastewater such as tertiary treated sewage. Perhaps as community attitudes and
trust in our technologies improve we will be able to “close the loop” – that is
fully recycle water directly.
- Colin Creighton, Director, Water for a Healthy Country,
CSIRO
GrahamTek has reduced the cost even more further
refining the process with the addition of flow
distributors on our membranes, and the use of
Electro magnetic field devices on saline water treatment systems.
BACK
IS IT POSSIBLE TO RUN A DESALINATION PLANT ON SOLAR ENERGY?
It is possible to run a desalination plant on solar energy alone, but at a much
smaller scale.
Solar energy is in the form of heat. Photovoltaic cells transfer this heat
energy into electrical energy, and this is then transferred into mechanical and
heat energy again. So it is not a terribly efficient solar energy source to use.
There are other types of solar energy, for example solar ponds, that don’t use
photovoltaic cells and can be incorporated into desalination plants.
Photovoltaic cells are very expensive as well.
Other sources of energy can be used, for example wind energy, or waste heat
produced in various industries such as the mineral processing industry or
especially in power generation industry where only 60 to 70% of the heat energy
is used. There is also the possibility of coupling solar energy with other
energy sources or using it as a supplementary source of energy, and this is
being looked at around the world.
BACK Do you think South Africa should be looking at new technology such
as desalination or be tackling the roots of our water shortage problems such as
unsustainable agriculture and urban use of water. Is desalination just another
quick fix? After all is appears that every time humans alter a natural system
other problems arise?
A lot of people are asking this question. There is no one solution to the
problem. I think desalination should be one of a number of strategies looked at
by people in a variety of disciplines in order to make sure we make the best use
of water and all our resources.
Desalination produces fresh water from saline water – essentially separating
salt from water. The saline water used could be seawater, but it could also be
water from leachate, or saline wastewater. Many people are looking at
desalination as a method to inject fresh water back into saline rivers or
aquifers to reduce damages done to the water.
The issue for human beings is to learn from Mother Nature to do it correctly.
After all, nature desalinates seawater in the evaporation of water from the
oceans to produce rain.
To design a desalination plant you need to assess the technology you are using,
how you can maximise the efficiency of the plant, and look at where the water
comes from, what type and quality of water you are dealing with, where it goes
to and what purpose it is required for, as well as how you use the concentrate
produced.
Many things need to be taken into account so we can benefit from desalination in
addition to using water efficiently.
BACK What happens to the excess salt produced by desalination? Is it
useful or just a waste product? If it is a waste product is it dumped out to sea
where it can potentially harm marine life?
The salt is usually a waste product from desalination. It is possible to make
salt products, such as Epsom salts etc, from the brine, but because the market
for these products is small and the price is cheap, it is usually not economic
to make products from the brine.
When seawater is desalinated, the brine is returned to the sea. This means that
the desalination process can operate with lower recoveries – you are not
recovering all of the water, but some of the water – leaving you with fresh
water and brine rather than water and salt, and so you use less energy per
metres cubed for the water produced. The brine is usually discharged to in a
location that allows it to be quickly dispersed, so its effect on the
environment can be minimised.
The mixing functions in the ocean are such that it does not harm marine life
unless there was no mixing at the release point, and that is avoided.
The brine generated as a wastewater during desalination is heavier than
seawater, so if incorrectly discharged to the ocean would sink to the bottom. In
addition, the brine is devoid of dissolved oxygen as a result of the
desalination process.
If it is released into calm water it can sink to the bottom as a plume of salty
water that can kill organisms on the sea bed from a lack of oxygen.
It's important to model the release of water to enable the design of appropriate
brine mixing and dispersion, so avoiding plume build-up on the sea bed.
The salt, especially because of the lack of oxygen in the plume, must be well
mixed and released, preferably by a high energy coastline.
GrahamTek does not use chemical agents in the treatment
of seawater, and therefore the brine reject portion of our process is in a
natural concentrated state. We have don various studies with institutions and
Universities to prove that our brine reject has no effect on Aqua marine life.
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